JPH037264B2 - - Google Patents
Info
- Publication number
- JPH037264B2 JPH037264B2 JP57184365A JP18436582A JPH037264B2 JP H037264 B2 JPH037264 B2 JP H037264B2 JP 57184365 A JP57184365 A JP 57184365A JP 18436582 A JP18436582 A JP 18436582A JP H037264 B2 JPH037264 B2 JP H037264B2
- Authority
- JP
- Japan
- Prior art keywords
- silicon
- electrolyte
- measuring
- electrode material
- standard electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052751 metal Inorganic materials 0.000 claims description 56
- 239000002184 metal Substances 0.000 claims description 56
- 229910052710 silicon Inorganic materials 0.000 claims description 43
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 41
- 239000010703 silicon Substances 0.000 claims description 41
- 239000003792 electrolyte Substances 0.000 claims description 38
- 239000007772 electrode material Substances 0.000 claims description 29
- 239000000523 sample Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 8
- 238000007598 dipping method Methods 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 2
- 230000000717 retained effect Effects 0.000 claims 1
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 22
- 238000005259 measurement Methods 0.000 description 19
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 9
- 230000005484 gravity Effects 0.000 description 6
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 235000012239 silicon dioxide Nutrition 0.000 description 6
- 239000000395 magnesium oxide Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- 229910052681 coesite Inorganic materials 0.000 description 3
- 229910052906 cristobalite Inorganic materials 0.000 description 3
- 239000011810 insulating material Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 239000010453 quartz Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 239000002893 slag Substances 0.000 description 3
- 229910052682 stishovite Inorganic materials 0.000 description 3
- 229910052905 tridymite Inorganic materials 0.000 description 3
- 229910052582 BN Inorganic materials 0.000 description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 2
- 229910017082 Fe-Si Inorganic materials 0.000 description 2
- 229910017133 Fe—Si Inorganic materials 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000011088 calibration curve Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 229910000805 Pig iron Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000004847 absorption spectroscopy Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000004993 emission spectroscopy Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000003779 heat-resistant material Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 150000003377 silicon compounds Chemical class 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000009628 steelmaking Methods 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by groups G01N1/00 - G01N31/00
- G01N33/20—Metals
- G01N33/205—Metals in liquid state, e.g. molten metals
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Food Science & Technology (AREA)
- Medicinal Chemistry (AREA)
- Physics & Mathematics (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
- Investigating And Analyzing Materials By Characteristic Methods (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP57184365A JPS5973763A (ja) | 1982-10-20 | 1982-10-20 | 溶融金属中の珪素量迅速測定方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP57184365A JPS5973763A (ja) | 1982-10-20 | 1982-10-20 | 溶融金属中の珪素量迅速測定方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5973763A JPS5973763A (ja) | 1984-04-26 |
JPH037264B2 true JPH037264B2 (en]) | 1991-02-01 |
Family
ID=16151953
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP57184365A Granted JPS5973763A (ja) | 1982-10-20 | 1982-10-20 | 溶融金属中の珪素量迅速測定方法 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5973763A (en]) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62127415A (ja) * | 1985-11-29 | 1987-06-09 | Nippon Steel Corp | 溶銑の脱珪方法 |
EP0285578B1 (en) * | 1987-03-27 | 1993-09-01 | CENTRO SVILUPPO MATERIALI S.p.A. | Improvement of electrochemical devices for measuring the silicon content of hot metal |
JPH0650296B2 (ja) * | 1987-11-17 | 1994-06-29 | 新日本製鐵株式会社 | 溶銑の燐濃度測定方法 |
US6013163A (en) * | 1997-07-18 | 2000-01-11 | Usx Corporation | Probe for detection of the concentration of various elements in molten metal |
-
1982
- 1982-10-20 JP JP57184365A patent/JPS5973763A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS5973763A (ja) | 1984-04-26 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR101768227B1 (ko) | 금속 용융물에서의 측정 및 샘플 채취용 측정 프로브 | |
US3773641A (en) | Means for determining the oxygen content of liquid metals | |
Distin et al. | Solubility of oxygen in liquid iron from 1785 to 1960 C. A new technique for the study of slag-metal equilibria | |
KR870000021B1 (ko) | 용융금속용 산소농도측정 센서(sensor) | |
US3752753A (en) | Method of fabricating a sensor for the determination of the oxygen content of liquid metals | |
US3864231A (en) | Apparatus for measuring in a continuous manner oxygen in a molten metal | |
JPH037264B2 (en]) | ||
US4098576A (en) | Method for analyzing the latent gas content of metal samples | |
JPH0246103B2 (en]) | ||
JPH0257866B2 (en]) | ||
JP3462993B2 (ja) | スラグ酸化度測定プローブ | |
US6328867B1 (en) | Sensors for measuring the solute contents of liquid ferrous and non-ferrous metals | |
Enaka et al. | Chemical potentials of oxygen within 3‐phase assemblages of the system CaO+ SiO2+ FexO | |
Iwase et al. | Tri‐phasic zirconia electrolyte for the in‐situ determinations of silicon activities in hot metal | |
JPS60231147A (ja) | 溶銑中の硅素量測定装置 | |
CA1062039A (en) | Molten metal sampling device and method with germanium killing agent | |
Pargeter et al. | Direct oxygen determination in commercial steelmaking practice | |
SUZUKI et al. | Application of Oxygen Probe to Steelmaking Process | |
JPH01131449A (ja) | 溶銑の燐濃度測定方法 | |
Björklund et al. | Effect of temperature on oxygen activity during ladle treatment | |
JPH0120691Y2 (en]) | ||
Iwase | Developments in Zirconia Sensors During the 1980 s--Laboratory and In-Plant Applications in Iron- and Steelmaking | |
JPS63255655A (ja) | 濃淡電池 | |
JPS6242008B2 (en]) | ||
ENGELL et al. | ELECTROCHEMICAL SENSING OF CARBON |